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Single-element detectors (SEDs) with a room temperature extended short-wave infrared (eSWIR) photoresponse were fabricated with branched nanorods of HgTe. Nanorods with high aspect (length/width) ratios were obtained by using stoichiometric excesses of Hg (i.e., [Hg]/[Te] molar ratios greater than one) and relatively low reaction temperatures, as low as room temperature. The size-tunable optical cutoff wavelengths of the detectors ranged from 2 to 3.5 μm, with specific detectivities as high as 2.4 × 10^11 Jones. The devices retained their responsivity for more than a year. Branched nanorods of HgTe are promising materials for IR photodetectors and imagers. 

Abstract Additive manufacturing systems that can arbitrarily deposit multiple materials into precise, 3D spaces spanning the micro‐ to nanoscale are enabling novel structures with useful thermal, electrical, and optical properties. In this companion paper set, electrohydrodynamic jet (e‐jet) printing is investigated for its ability in depositing multimaterial, multilayer films with microscale spatial resolution and nanoscale thickness control, with a demonstration of this capability in creating 1D photonic crystals (1DPCs) with response near the visible regime. Transfer matrix simulations are used to evaluate different material classes for use in a printed 1DPC, and commercially available photopolymers with varying refractive indices (n= 1.35 to 1.70) are selected based on their relative high index contrast and fast curing times. E‐jet printing is then used to experimentally demonstrate pixelated 1DPCs with individual layer thicknesses between 80 and 200 nm, square pixels smaller than 40 µm across, with surface roughness less than 20 nm. The reflectance characteristics of the printed 1DPCs are measured using spatially selective microspectroscopy and correlated to the transfer matrix simulations. These results are an important step toward enabling cost‐effective, custom‐fabrication of advanced imaging devices or photonic crystal sensing platforms.